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Online ISSN: 1521-3773    Print ISSN: 1433-7851
Angewandte Chemie International Edition
Volume 41, Issue 20, 2002.

© 2002 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

 

PDF  3723  Cover Picture: Angew. Chem. Int. Ed. 20/2002
Christoph Schaffrath, Steven L. Cobb, David O'Hagan

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3723::AID-ANIE3723>3.0.CO;2-O

 Graphical Abstract
 
PDF  3725-3738  Graphical Abstract: Angew. Chem. Int. Ed. 20/2002


Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3725::AID-ANIE3725>3.0.CO;2-C

 Corrigendum
 
PDF  3738  Mechanistic Features, Cooperativity, and Robustness in the Self-Assembly of Multicomponent Silver(I) Grid-Type Metalloarchitectures
Annie Marquis, Jean-Pierre Kintzinger, Roland Graff, Paul N. W. Baxter, Jean-Marie Lehn

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3738::AID-ANIE3738>3.0.CO;2-T

 Review
 
PDF  3746-3766  A Concept for Synthesis Planning in Solid-State Chemistry
Martin Jansen

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3746::AID-ANIE3746>3.0.CO;2-2

 Minireview
 
PDF  3767-3774  The Structures of Integrins and Integrin-Ligand Complexes: Implications for Drug Design and Signal Transduction
Kay-E. Gottschalk, Horst Kessler

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3767::AID-ANIE3767>3.0.CO;2-T

 Highlight
 
PDF  3775-3778  Asymmetric Hydrovinylation: New Perspectives through Use of Modular Ligand Systems
Lukas J. Gooßen

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3775::AID-ANIE3775>3.0.CO;2-2

PDF  3779-3783  Nanomechanical Devices Based on DNA
Christof M. Niemeyer, Michael Adler

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3779::AID-ANIE3779>3.0.CO;2-F

 Communication
 
PDF  3785-3789  Rhodium Tetracarbonyl Hydride: The Elusive Metal Carbonyl Hydride
Chuanzhao Li, Effendi Widjaja, Wee Chew, Marc Garland

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3785::AID-ANIE3785>3.0.CO;2-0

PDF  3789-3793  Spontaneous Deposition of Water-Soluble Substances into Microcapsules: Phenomenon, Mechanism, and Application
Changyou Gao, Edwin Donath, Helmuth Möhwald, Jiacong Shen

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3789::AID-ANIE3789>3.0.CO;2-D

PDF  3793-3796  Solid-State and Solution Studies of a Tetrameric Capsule and Its Guests
Darren W. Johnson, Fraser Hof, Peter M. Iovine, Colin Nuckolls, Julius Rebek, Jr.

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3793::AID-ANIE3793>3.0.CO;2-A

PDF  3796-3799  The Supercritical Fluid Antisolvent Synthesis of C60(C2Hx) (x=4 or 6); The Crystal Structures of Two Materials Which Were Thought Unlikely to Exist
Adam O'Neil, Claire Wilson, Jeremy M. Webster, Francis J. Allison, Judith A. K. Howard, Martyn Poliakoff

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3796::AID-ANIE3796>3.0.CO;2-T

PDF  3800-3803  Novel, Acentric Metal-Organic Coordination Polymers from Hydrothermal Reactions Involving In Situ Ligand Synthesis
Ren-Gen Xiong, Xiang Xue, Hong Zhao, Xiao-Zeng You, Brendan F. Abrahams, Ziling Xue

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3800::AID-ANIE3800>3.0.CO;2-3

PDF  3804-3807  Probing the Spatial Distribution and Morphology of Supported Nanoparticles Using Rutherford-Scattered Electron Imaging
Paul A. Midgley, Matthew Weyland, John Meurig Thomas, Pratibha L. Gai, Edward D. Boyes

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3804::AID-ANIE3804>3.0.CO;2-G

PDF  3807-3809  Methyl Transfer from Rhenium to Coordinated Thiolate Groups
Xiaopeng Shan, Arkady Ellern, James H. Espenson

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3807::AID-ANIE3807>3.0.CO;2-Z

PDF  3809-3811  Naked-Eye Detection of Phosphate Ions in Water at Physiological pH: A Remarkably Selective and Easy-To-Assemble Colorimetric Phosphate-Sensing Probe
Min Su Han, Dong H. Kim

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3809::AID-ANIE3809>3.0.CO;2-N

PDF  3811-3814  Pyrophosphate Detection in Water by Fluorescence Competition Assays: Inducing Selectivity through the Choice of the Indicator
Luigi Fabbrizzi, Nathalie Marcotte, Floriana Stomeo, Angelo Taglietti

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3811::AID-ANIE3811>3.0.CO;2-W

PDF  3815-3817  SASAPOS, not Sisyphos: Highly Efficient 20-Step One-Pot Synthesis of a Discrete Organic-Inorganic Ion Cluster with a Porphyrin Core
Robert Weiss, Frank Pühlhofer, Norbert Jux, Klaus Merz

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3815::AID-ANIE3815>3.0.CO;2-8

PDF  3818-3822  Syntheses and Crystal Structures of the New Ag-S Clusters [Ag70S16(SPh)34(PhCO2)4(triphos)4] and [Ag188S94(PR3)30]
Xiu-Jian Wang, Timo Langetepe, Claudia Persau, Bei-Sheng Kang, George M. Sheldrick, Dieter Fenske

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3818::AID-ANIE3818>3.0.CO;2-R

PDF  3823-3825  Targeted Synthesis of Ferromagnetically Coupled Complexes with Modified 1,3,5-Trihydroxybenzene Ligands
Thorsten Glaser, Mareike Gerenkamp, Roland Fröhlich

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3823::AID-ANIE3823>3.0.CO;2-I

PDF  3825-3829  Supramolecular Engineering with Macromolecules: An Alternative Concept for Block Copolymers
Bas G. G. Lohmeijer, Ulrich S. Schubert

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3825::AID-ANIE3825>3.0.CO;2-6

PDF  3829-3832  Unusual PC Bond Cleavage by Double Dichlorosilylene Transfer from Trichlorosilyltrimethylgermane to P-Phosphanyl Phosphaalkenes
Wolf-Walther du Mont, Thorsten Gust, Emma Seppäl? Cathleen Wismach, Peter G. Jones, Ludger Ernst, Jörg Grunenberg, Heinrich C. Marsmann

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3829::AID-ANIE3829>3.0.CO;2-J

PDF  3832-3834  Fluoroformic Acid Anhydride, FC(O)OC(O)F
Holger Pernice, Helge Willner, Karina Bierbrauer, Maximiliano Burgos Paci, Gustavo A. Argüello

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3832::AID-ANIE3832>3.0.CO;2-M

PDF  3835-3838  A Self-Generating, Highly Active, and Recyclable Olefin-Metathesis Catalyst
Stephen J. Connon, Aideen M. Dunne, Siegfried Blechert

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3835::AID-ANIE3835>3.0.CO;2-4

PDF  3839-3841  Synthesis of A,B-Alternating Copolymers by Ring-Opening-Insertion-Metathesis Polymerization
Tae-Lim Choi, Isaac M. Rutenberg, Robert H. Grubbs

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3839::AID-ANIE3839>3.0.CO;2-H

PDF  3841-3844  Polymerase Recognition of Unnatural Base Pairs
Chengzhi Yu, Allison A. Henry, Floyd E. Romesberg, Peter G. Schultz

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3841::AID-ANIE3841>3.0.CO;2-Q

PDF  3844-3848  Hierarchically Ordered Silica Mesophases Using Mixed Surfactant Systems as Templates
An-Wu Xu, Yue-Peng Cai, Hua-Xin Zhang, Li-Zhi Zhang, Jimmy C. Yu

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3844::AID-ANIE3844>3.0.CO;2-8

PDF  3848-3851  4,4-Diphenyl-2,5-cyclohexadienone: Four Polymorphs and Nineteen Crystallographically Independent Molecular Conformations
V. S. Senthil Kumar, Anthony Addlagatta, Ashwini Nangia, Ward T. Robinson, Charlotte K. Broder, Raju Mondal, Ivana R. Evans, Judith A. K. Howard, Frank H. Allen

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3848::AID-ANIE3848>3.0.CO;2-L

PDF  3852-3854  Heterogeneous Pd-Catalyzed Asymmetric Allylic Substitution Using Resin-Supported Trost-Type Bisphosphane Ligands
Choong Eui Song, Jung Woon Yang, Eun Joo Roh, Sang-gi Lee, Jou Hyeon Ahn, Hogyu Han

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I

PDF  3854-3857  Noncovalent Chemistry of Nitrous Oxide: Interactions with Secondary cis Amides in Solution
Grigory V. Zyryanov, Erin M. Hampe, Dmitry M. Rudkevich

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3854::AID-ANIE3854>3.0.CO;2-6

PDF  3858-3860  Insertion and Cycloaddition Reactivity of a Transition-Metal N-Metalloimine
Eva Hevia, Julio Pérez, Víctor Riera, Daniel Miguel

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3858::AID-ANIE3858>3.0.CO;2-J

PDF  3860-3862  An Iridaborane Reaction Cycle Driven by PMe3 and BH3THF: Synthesis and Characterization of [Cp*IrB3H7(PMe3)] and [Cp*IrB2H6(PMe3)]
Ramón Macías, Thomas P. Fehlner, Alicia M. Beatty

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3860::AID-ANIE3860>3.0.CO;2-S

PDF  3863-3865  A Crystalline -Hairpin Peptide Nucleated by a Type I Aib-D-Ala -Turn: Evidence for Cross-Strand Aromatic Interactions
Subrayashastry Aravinda, Narayanaswamy Shamala, Rai Rajkishore, Hosahudya N. Gopi, Padmanabhan Balaram

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3863::AID-ANIE3863>3.0.CO;2-A

PDF  3866-3870  A New Method for the Synthesis of Nonsymmetrical Sulfamides Using Burgess-Type Reagents
K. C. Nicolaou, Deborah A. Longbottom, Scott A. Snyder, Annie Z. Nalbanadian, Xianhai Huang

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3866::AID-ANIE3866>3.0.CO;2-T

PDF  3870-3873  [OsIII(tpy)(Cl)(NCCH3)(NSAr)]: Reversible Reduction of Acetonitrile by OsIII-Sulfilimido Complexes
My Hang V. Huynh, R. Thomas Baker, David E. Morris, Peter S. White, Thomas J. Meyer

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3870::AID-ANIE3870>3.0.CO;2-Q

PDF  3873-3876  The Ability of the ,-Diiminopyridine Ligand System to Accept Negative Charge: Isolation of Paramagnetic and Diamagnetic Trianions
David Enright, Sandro Gambarotta, Glenn P. A. Yap, Peter H. M. Budzelaar

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3873::AID-ANIE3873>3.0.CO;2-8

PDF  3876-3878  Room-Temperature Synthesis in Acidic Media of Large-Pore Three-Dimensional Bicontinuous Mesoporous Silica with Ia3d Symmetry
Xiaoying Liu, Bozhi Tian, Chengzhong Yu, Feng Gao, Songhai Xie, Bo Tu, Renchao Che, Lian-Miao Peng, Dongyuan Zhao

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3876::AID-ANIE3876>3.0.CO;2-R

PDF  3878-3881  Transmembrane Signalling
Patrick Barton, Christopher A. Hunter, Timothy J. Potter, Simon J. Webb, Nicholas H. Williams

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3878::AID-ANIE3878>3.0.CO;2-F

PDF  3882-3884  Electric-Field-Modulated Circular-Difference Effects in Second-Harmonic Generation from a Chiral Liquid Crystal
Thierry Verbiest, Sonja Sioncke, Andr?Persoons, Libor Vyklick? Thomas J. Katz

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3882::AID-ANIE3882>3.0.CO;2-C

PDF  3884-3887  Diastereoselective Lithiation of (6-Arene)dicarbonyltriphenylphosphane Chromium(0) Oxazoline Complexes - Direct Preparation of Enantiopure Complexes Having Planar Chiral Fragments of Either Configuration
Larry E. Overman, Carolyn E. Owen, G. Greg Zipp

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3884::AID-ANIE3884>3.0.CO;2-0

PDF  3887-3889  Enantioselective Synthesis of Substituted Pyrrolidines by Dynamic Resolution
Iain Coldham, Samuel Dufour, Thomas F. N. Haxell, Steven Howard, Graham P. Vennall

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3887::AID-ANIE3887>3.0.CO;2-J

PDF  3890-3892  Water-Insoluble Lanthanum Oxychloride-Based Solid Electrolytes with Ultra-High Chloride Ion Conductivity
Nobuhito Imanaka, Koji Okamoto, Gin-ya Adachi

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3890::AID-ANIE3890>3.0.CO;2-M

PDF  3892-3894  Application of a New Family of P,N Ligands to the Highly Enantioselective Hydrosilylation of Aryl Alkyl and Dialkyl Ketones
Beata Tao, Gregory C. Fu

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3892::AID-ANIE3892>3.0.CO;2-A

PDF  3894-3896  Design Optimization of 1,3-Diphospha-2,4-diboretane Diradicals
Mark Seierstad, Christopher R. Kinsinger, Christopher J. Cramer

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3894::AID-ANIE3894>3.0.CO;2-Z

PDF  3897-3898  Naphtho[1,8-b,c]phosphete and 1,2-Diphosphaacenaphthene from the Reaction of 1,8-Dilithionaphthalene with RPCl2
Tsutomu Mizuta, Tooru Nakazono, Katsuhiko Miyoshi

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3897::AID-ANIE3897>3.0.CO;2-H

PDF  3898-3901  Butane-2,3-diacetals of Glyceraldehyde: A Stable Alternative to Glyceraldehyde Acetonide
Patrick Michel, Steven V. Ley

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3898::AID-ANIE3898>3.0.CO;2-B

PDF  3901-3903  Highly Efficient Catalytic Synthesis of Substituted Allenes Using Indium
Kooyeon Lee, Dong Seomoon, Phil Ho Lee

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3901::AID-ANIE3901>3.0.CO;2-S

PDF  3905-3907  Ethane and Ethylidene Dicarboxylates from the Ruthenium(II)-Catalyzed Disproportionative Addition of Carboxylic Acids to Ethene
Tiziana Funaioli, Fabio Marchetti, Giuseppe Fachinetti

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3905::AID-ANIE3905>3.0.CO;2-4

PDF  3907-3910  Selective Measurements of a Nitroxide-Nitroxide Separation of 5 nm and a Nitroxide-Copper Separation of 2.5 nm in a Terpyridine-Based Copper(II) Complex by Pulse EPR Spectroscopy
Evelyn Narr, Adelheid Godt, Gunnar Jeschke

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3907::AID-ANIE3907>3.0.CO;2-T

PDF  3910-3912  Suzuki Cross-Couplings of Alkyl Tosylates that Possess Hydrogen Atoms: Synthetic and Mechanistic Studies
Matthew R. Netherton, Gregory C. Fu

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3910::AID-ANIE3910>3.0.CO;2-W

PDF  3913-3915  Cell-Free Biosynthesis of Fluoroacetate and 4-Fluorothreonine in Streptomyces cattleya
Christoph Schaffrath, Steven L. Cobb, David O'Hagan

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3913::AID-ANIE3913>3.0.CO;2-E

 Book Review
 
PDF  3917  Book Review: High Performance Pigments. Edited by Hugh M. Smith
Gerald Fuchs-Pohl

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3917::AID-ANIE3917>3.0.CO;2-R

PDF  3917-3918  Book Review: Pharmaceutical Chemistry. Therapeutic Aspects of Biomacromolecules. By Christine M. Bladon
Robert J. Linhardt

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3917::AID-ANIE11113917>3.0.CO;2-J

PDF  3918-3919  Book Review: Nationalizing Science. Adolphe Wurtz and the Battle for French Chemistry. by Alan J. Rocke
Paul Knochel

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3918::AID-ANIE3918>3.0.CO;2-L

PDF  3919  Book Review: Free Energy Calculations in Rational Drug Design. Edited by M. Rami Reddy and Mark D. Erion
Volkhard Helms

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3919::AID-ANIE3919>3.0.CO;2-F

PDF  3919-3920  Book Review: Organic Synthesis Engineering. By L. K. Doraiswamy
Jörg Unger, Ralf Böhling

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3919::AID-ANIE11113919>3.0.CO;2-7

PDF  3920-3921  Book Review: Handbook of Vibrational Spectroscopy. Vols. 1-5. Edited by John M. Chalmers and Peter R. Griffiths
Hans Bettermann

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3920::AID-ANIE3920>3.0.CO;2-U

 Web Site
 
PDF  3923  Web Site: And The Winner Is
Yaron Rapaport

Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3923::AID-ANIE3923>3.0.CO;2-C

 Preview
 
PDF  3926  Preview: Angew. Chem. Int. Ed. 20/2002


Published Online: 18 Oct 2002
DOI10.1002/1521-3773(20021018)41:20<3926::AID-ANIE3926>3.0.CO;2-V



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